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Both Molybdenum and Uranium Vital for Nuclear Reactors

Molybdenum plays a more vital role in the greatest numbers of new constructions are
global nuclear renaissance than you might expected from China, India, Japan,
suspect. Without the silvery white Russia, South Korea and Japan (and
metal, the world's energy infrastructure possibly the United States).
would somewhat suffer. But, nuclear power Existing reactors along coastal areas in
plants would be set back at least two Asian countries presently breaks down as
decades. The new high performance follows: Japan (57), South Korea (26),
stainless steels (HPSS) contain as much China and Taiwan (19) and India (11).
as 7.5 percent molybdenum and can add Because these are the most prone to
more than three times the life to the seawater or brackish corrosion, they are
world's aging nuclear fleet condenser also the likely candidates for upgrading
tubes. existing condenser tubing to high alloy
During the early construction of nuclear stainless steel. And their new reactors
power plants, steam condensers relied are likely going to be constructed along
upon copper base alloys - brass and their coasts, requiring the super
copper nickel - for heat transfer austenitic grades. As an aside, of the
capabilities. These alloys have high previously mentioned 190 nuclear power
coefficients of thermal conductivity plants which had replaced their
required in steam generation to power condensers with HPSS, 45 percent used
nuclear reactor turbines. But fresh water as coolant. Those plants
copper-alloyed tubes were being replaced chose the high alloy steel as a
too quickly - with an average life of 'fail-safe' measure to prevent
eight years - because of sulphide interrupted service or a potential
pitting. Hardest hit were those reactors reactor incident.
using polluted seawater to cool their The United Nations estimates that
reactors. two-thirds of the planet's population
Over the past 30 years ago, nuclear will be living with water stress by 2025.
utilities slowly began turning to the Global freshwater scarcity may demand the
super austenitic stainless steels as one use of brackish or seawater as nuclear
way to make their nuclear reactors last reactor coolant. To prevent the
longer. The addition of molybdenum, accompanying corrosion, the
initially starting with percentage of higher-percentage molybdenum alloy,
less than four percent, helped increase specifically the 654 SMOÂ(R), could
the thermal conductivity lacking in emerge as the condenser tubing material
nickel, iron or steel. At nuclear of choice. Either the 254 SMOÂ(R) or the
stations which replaced the copper alloys 654 would be utilized in desalination
with HPSS condenser tubes, 57 percent plants required to overcome water
rated the thermal performance good and shortages in the hardest hit areas: North
all but one rated it normal. Molybdenum Africa, the Middle East and West Asia.
had helped overcome the thermal hurdle. Typically, nuclear power plant condenser
A large number of the 190 nuclear tubing requires approximately 520,000
reactors, which now utilize HPSS feet of stainless steel. According to the
condenser tubes, reported an average life International Molybdenum Association
in excess of 18 years. The longest (IMOA), larger reactors could utilize up
stainless steel condenser installation to one million feet of stainless steel.
has remained in service more than 26 With the higher molybdenum grades found
years, according to a study done several in the super alloys, new nuclear reactors
years ago. According to a report could require tens of thousands of metric
published in 2000, more than 100 million tons of molybdenum.
feet of super-alloy stainless steel tubes By comparison, nuclear waste containers
have replaced the older, copper-alloy proposed for the Yucca Mountain nuclear
tubing. waste repository were forecast to consume
Condensers are large heat exchangers used about 15,000 metric tons of moly. While
in nuclear power plants. Condensers have this project may or may not proceed as
thousands of tubes horizontally mounted planned to the construction phase, the
to condense and recover the steam passing Nuclear Energy Institute (NEI) has
through turbines. Each low-pressure proposed regionalized storage of spent
turbine generally has a condenser, which fuel.
also maintains a vacuum to optimize the Should comparably designed storage
turbine's efficiency. canisters be utilized to 'temporarily'
Water fouling deposits were cited as a contain the nuclear waste, it is likely
major problem at many reactors, molybdenum will play a key role.
especially with condenser tubes where According to the U.S. Government's Energy
seawater or high-chloride brackish water Citation Database, as published by the
was the coolant. Pitting corrosion, tube Department of Energy's Office of
sheet crevice corrosion and galvanic Scientific and Technical Information,
corrosion put the tubes at risk for "Alloys with combined chromium plus
leakage. Plugging, mud, or detritus molybdenum contents greater than 30
accumulating in condenser tubes reduce a percent were the most resistant to
power plant's efficiency. general and local attack." This was the
Utilities use cleaning systems with conclusion reached after corrosion
small, abrasive sponge-like balls to keep scouring tests were performed on
the tubes clean and test for tube stainless steel and nickel-based alloys
defectives with probing devices. Tube to immobilize high-level, radioactive
thinning and corrosion create the waste. Another aspect where
opportunity for tube leakage. This can high-percentage molybdenum stainless
not be tolerated because chemicals such steel would double up is with the
as sodium and chlorides find their way expansion of nuclear desalination plants.
into the reactor vessel or steam In the past, and in our publication,
generator. "Investing in the Great Uranium Bull
Upgrading the steam condenser tubing to Market," we have discussed the rise of
stainless steel also plays a vital role nuclear desalination across those coastal
in the 'power uprate' program utilities areas, requiring far more freshwater than
have used to increase generating capacity can possibly be transported through other
for existing reactors as we recently means. The World Nuclear Association
discussed. The more advanced uprate (WNA) has reported of numerous such
program could add up to 20-percent desalination projects in progress.
capacity to existing U.S. nuclear Will The Energy Bull Have Sufficient
reactors. Moly?
Different Molybdenum Alloys From nearly every energy project - oil,
There are several HPSS manufacturers for gas, coal and nuclear, and for water,
nuclear reactor condensers. The most molybdenum demand will continue
prominent in the nuclear sector include increasing. Super austenitic grades
Pennsylvania-based ATI Allegheny Ludlum demand a higher moly content to combat
and Finland's Outokumpu. Each offers corrosion and provide reliability of
austenitic steels with chromium and service. Of course, there will be
nickel composition of between 20 and 25 substitution in the face of future supply
percent for each alloy and a range of 6.2 shortfalls. In some instances, there are
to 7.5 percent molybdenum. reports the Russians have substituted
In a paper presented by Jan Olsson of vanadium for molybdenum in some of their
Avesta Sheffield (before the company was oil and gas pipelines to conserve on moly
acquired by Outokumpu), he highlighted consumption. ATI Allegheny Ludlum has
the results of tests performed on the new argued for the substitution of
super-austenitic stainless steel, 654 two-percent manganese for every percent
SMOÂ(R). Metals comprising this brand of nickel, but in the lower grade
include 25-percent chromium, 22-percent austenitic groups which do not demand the
nickel and 7.5-percent molybdenum. To corrosion resistance of energy projects.
increase pitting resistance, the While reviewing the anticipated new
manufacturers added up to 0.5-percent projects from the molybdenum mining
nitrogen and three-percent manganese (for sector, we foresee the high probability
make the nitrogen more soluble). of supply inadequacy. Aside from China
As with all pioneering developments - and Moly's Sandaozhuang molybdenum mine,
remember that R & D breakthroughs have which the company hopes could produce
taken place over a two-decade-plus 28,000 tonnes of molybdenum concentrate
period, manufacturers have re-designed this year and perhaps grow by another 17
their metallurgical composition to find percent the following year, there is a
the most encouraging percentages of paucity of new molybdenum projects coming
nickel, chromium, molybdenum and fully online before 2009.
nitrogen. The earlier stainless steels Based upon China's voracious appetite for
relied on higher nickel content and molybdenum - one research firm estimated
lesser percentages of chromium and compounded annual growth rate over the
molybdenum. previous five years at 17 percent,
At first, conventional austenitic grades, whatever excess moly production comes
such as 316L, or high chromium-ferritic from China Moly's mining efforts could
grades, were utilized. Pitting struck very well be domestically consumed.
down widespread use of the 316L series Future North American molybdenum
and was replaced by higher alloy steels. producers may need to ramp up their
For example, others, such as the 254 projects to meet the growing demand.
SMOÂ(R) stainless steel, began During 2006, demand grew above the
aggressively replacing the copper alloy historical norm of four percent; most of
tubes and in some cases the 316L series. the consumption came from China. This is
The 254 is comprised of 20-percent unlikely to stagnate or decrease, and
chromium, 18-percent nickel, 6.2-percent could interfere with North American and
molybdenum and 0.20-percent nitrogen. It European consumption of molybdenum.
has also offered a high level of Only one company is scheduled to commence
corrosion resistance at desalination molybdenum mining in 2007, Roca Mines.
plants without becoming cost-prohibitive. Because the company is limited to a
The most significant breakthrough came small-mining permit, anticipated
after various stainless steels were production could not exceed three million
tested at Scandinavian coastal reactors. pounds. By late 2008, or early 2009,
In the Avesta paper, the failures of each Adanac Molybdenum hopes to commence its
lesser austenitic grade were checked off. start-up efforts to reach eight-figure
Significant deficiencies included moly production. Later, Blue Pearl Mining
insufficient stress corrosion cracking hopes to commence high-grade molybdenum
resistance and resistance to natural mining at the Davidson deposit in British
seawater. Even titanium tubing was used Columbia. Around this time, the Climax
as an interim measure because it molybdenum mine could re-open and begin
increased total heat transfer by 17 production in Colorado. Moly Mines hopes
percent, but the metal failed to stand up to begin production at the company's
to high velocity steam and suffered Spinifex project. Possibly, before the
'water droplet erosion.' decade ends, Idaho General might commence
According to the study, "The only alloy operations in Nevada. Perhaps before
fully resistant to all test conditions those 48 nuclear reactors come online, US
was 654 SMOÂ(R)." The results at nuclear Energy's Mt. Emmons deposit may be mined
power plants in Finland and Sweden, along in Colorado.
the Baltic Sea, were astonishing! Four Many of these projects are subject to
important conclusions about this super environmental permitting and/or
alloy were reached after the testing. financing, putting any material amount of
· Its corrosion resistance could cope forecasted supply in jeopardy. And this
with the hostile environments existing comes at a time when some experts believe
inside condenser tubes of desalination byproduct molybdenum production at copper
plants and power plants. mines could be constrained. There are
· Its corrosion resistance was good many conditional requirements which do
enough to cop with many other hostile not necessarily guarantee a reliable
brine and seawater environments. supply from the new breed of primary moly
· Its erosion resistance was producers. We have witnessed comparable
advantageous where it was exposed to high obstacles in the uranium sector, which
velocity streams. has since been accompanied by a
· There was no concern about its heat hyperbolic price rally in this metal.
transfer characteristics. There could come a point in the
Nuclear Consumption of Molybdenum molybdenum sector where the silvery white
About 48 nuclear reactors are reportedly metal could mimic such a breakout
scheduled for construction by 2013. It scenario. Nearly three years ago,
may be possible that up to 100 could be featured a forecast of US$100/pound
constructed by 2020, depending upon uranium. No one believed that prediction
political and financial climates. The at the time. On Friday, TradeTech
largest number proceeding through the announced a spot price of US$113/pound.
proposed, planned or construction phases COPYRIGHT© 2007 by StockInterview,
will be located along coastal areas to Inc. ALL RIGHTS RESERVED.
service the most populated areas. The




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